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Methanol (Methyl Alcohol)

CAS: 67-56-1 Category: Industrial ⚠ DANGER
Also known as: Methyl alcohol, Wood alcohol, Columbian spirits, MeOH

Quick Facts

CAS Number67-56-1
Signal WordDANGER
GHS Hazard Classesflammable, toxic
NFPA RatingHealth: 1 / Flammability: 3 / Reactivity: 0
Common NamesMethyl alcohol, Wood alcohol, Columbian spirits, MeOH
PubChem CID887

Hazard Summary

⚠ DANGER: Simple primary alcohol that is extremely toxic — as little as 10 mL can cause permanent blindness; 30 mL can be fatal. Metabolized to formaldehyde and formic acid. Cannot be distinguished from ethanol by sight or smell.

GHS Hazard Pictograms

🔥 Flammable ☠ Acutely Toxic

Hazard Statements (H-codes)

H225 – Highly flammable liquid and vapour
H301+H311+H331 – Toxic if swallowed, skin contact, or inhaled
H370 – Causes damage to organs (eyes, CNS)
H370 – Causes damage to organs (optic nerve)

Precautionary Statements (P-codes)

P210 – Keep away from heat/sparks
P260 – Do not breathe vapours
P301+P310 – IF SWALLOWED: Immediately call Poison Control
P311 – Call Poison Control

First Aid Measures (Section 4)

👁 Eye Contact
Flush with water for 15 minutes. Methanol vapour can damage the optic nerve. Seek immediate medical attention.
🖐 Skin Contact
Wash with soap and water. Remove contaminated clothing. Absorbed through skin — seek medical evaluation for significant dermal exposure.
🫁 Inhalation
Move to fresh air immediately. Methanol is absorbed by inhalation. Seek medical attention for any significant exposure.
🫦 Ingestion
MEDICAL EMERGENCY — call 911 and Poison Control (1-800-222-1222) immediately. Antidote (fomepizole or ethanol IV) must be given within hours to prevent permanent blindness and death.

Storage & Handling

🔒 Storage & Handling: Flammable storage cabinet. Keep away from heat, ignition sources, and oxidizers. Clearly label all containers.

PPE Requirements

Chemical splash goggles
Butyl rubber or nitrile gloves
Organic vapour respirator
Flame-resistant clothing
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